New light on the photocatalytic performance of NH4V4O10 and its composite with rGO

Scientific Reports volume 13, Article number: 3946 (2023) Cite this article

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Solar-driven photocatalysis has shown great potential as a sustainable wastewater treatment technology that utilizes clean solar energy for pollutant degradation. Consequently, much attention is being paid to the development of new, efficient and low-cost photocatalyst materials. In this study, we report the photocatalytic activity of NH4V4O10 (NVO) and its composite with rGO (NVO/rGO). Samples were synthesized via a facile one-pot hydrothermal method and successfully characterized using XRD, FTIR, Raman, XPS, XAS, TG-MS, SEM, TEM, N2 adsorption, PL and UV‒vis DRS. The results indicate that the obtained NVO and NVO/rGO photocatalysts exhibited efficient absorption in the visible wavelength region, a high content of V4+ surface species and a well-developed surface area. Such features resulted in excellent performance in methylene blue photodegradation under simulated solar light illumination. In addition, the composite of NH4V4O10 with rGO accelerates the photooxidation of the dye and is beneficial for photocatalyst reusability. Moreover, it was shown that the NVO/rGO composite can be successfully used not only for the photooxidation of organic pollution but also for the photoreduction of inorganic pollutants such as Cr(VI). Finally, an active species trapping experiment was conducted, and the photodegradation mechanism was discussed.

Population growth and rapid urbanization adversely affect the aqueous environment. Every day, industries, agriculture and households generate copious amounts of wastewater that can pollute rivers, lakes and seas. One of the major concerns is organic contaminations such as dyes or antibiotics, which are usually toxic and nonbiodegradable1. Even low concentrations of dyes in water systems can be very dangerous for aquatic life due to the blocking of sunlight required for photosynthesis2,3. Another hazardous group of pollutants is heavy metal ions, which are highly soluble in aquatic environments and nonbiodegradable and therefore tend to accumulate in living organisms either directly or through the food chain4. The toxic effect of many heavy metals is indisputable, and in many cases, exposure to trace amounts of these metals can cause serious damage to human health and the ecosystem5. For example, Cr(VI) is highly carcinogenic. U.S. Environmental Protection Agency listed it in the top 20 on the Hazardous Substance Priority List6, while the recommended WHO safe limit of Cr(VI) in drinking water equals 0.1 ppm7. Unfortunately, industrial wastewater coming from the manufacturing of paints, papers, preservatives or metal surface treatment (electroplating) can still be listed as the main source of Cr(VI). Hence, it is very important to remove the abovementioned pollutants from wastewater and protect the environment. Many methods of treating wastewater have been proposed, such as adsorption, filtration, coagulation, or photocatalytic degradation8. In particular, the latter is highly promising since it not only removes contaminations but also leads to their decomposition. Thus, compared to other popular methods in which contaminants are transferred from one phase to another, photocatalysis wins because of the absence of secondary pollution. Moreover, the process is usually fast, often uses a natural source of light and can be carried out under ambient conditions. Due to the above advantages, searching and developing new photocatalytic materials is an important ongoing research topic9,10. Among the various materials, metal oxides have been extensively investigated for the photodegradation of water pollutants11,12. Vanadium-based oxides are particularly promising because of their efficient visible light-harvesting ability (owing to their narrow band gap, Eg ̴2eV), high chemical stability and significant catalytic activity13,14. Many metal vanadates have been proposed as promising solar-driven photocatalysts. Examples include Cu3V2O815, Ag3VO4/AgVO316, InVO417 or BiVO418, which are the most well-known catalysts in this field. Recently, we proposed using a simple potassium salt (potassium formate) as a promising alternative for the synthesis of visible-light-driven photocatalysts. The obtained potassium vanadates (KV3O8, K2V6O16•nH2O) exhibited excellent photocatalytic activity, resulting in more than 90% degradation of methylene blue (MB) within the first 30 min19.

In this study, we present an efficient NH4V4O10 photocatalyst that is composed of NH4+ instead of metallic cations and can be synthesized via a facile hydrothermal method from an easily accessible NH4VO3 precursor. Moreover, we propose to combine it with rGO and investigate for the first time the use of such a composite for the photodegradation of water pollutants. The idea of the combination of vanadates with rGO to enhance the photocatalytic properties is known from the literature. It was already shown that the transfer of excited electrons from vanadate to rGO is possible in such composites20. This phenomenon can positively affect e-/h + separation and inhibit the adverse recombination process. Usually, the preparation of vanadate/rGO composites requires two steps: separate synthesis of vanadates and their further reaction with carbonaceous materials. A huge advantage of the proposed NH4V4O10/rGO composite is its one-pot synthesis, involving simultaneous hydrothermal reduction of NH4VO3 and GO. Notably, the NH4V4O10/rGO composite was already reported and proposed as an efficient electrode material for capacitive deionization21 and aqueous zinc-ion batteries22,23. However, it has never been tested in photocatalytic applications.

The photocatalytic activity of synthesized NH4V4O10 and NH4V4O10/rGO was evaluated towards the oxidation of methylene blue and the reduction of Cr(VI) under simulated solar light illumination. The excellent performance in MB photodegradation is attributed to the high content of V4+ surface species (which promotes charge carrier separation) as well as the developed surface area (which ensures more active sites for the adsorption and photocatalysis process). Moreover, we show that the combination of NH4V4O10 with rGO widens its application, and the proposed composite can be used not only for photooxidation of organic pollution but also for photoreduction of inorganic pollutants with Cr(VI) as an example. The addition of rGO also enhances light absorption in the visible region, accelerates the photooxidation reaction, and ensures cyclic stability.

The XRD patterns of NVO and NVO/rGO are presented in Fig. 1a. All diffraction reflexes correspond well with the ammonium vanadate phase NH4V4O10, PDF no. 230493 (ICSD), which corresponds to a monoclinic structure with lattice parameter values of a = 11.57 Å, b = 3.65 Å, and c = 9.81 Å)24,25, which is characterized by a layered structure built from corner-shared VO6 layers and NH4+ cations between them. The strongest line corresponds to the 001 plane, which indicates preferential growth along the c-axis. The absence of any other reflexes indicates that a pure phase was obtained for both samples. In addition, characteristic diffraction reflexes of rGO were not observed for the NVO/rGO composite due to the intrinsic weak diffraction intensities of the graphene phase. Moreover, it has also been reported that no rGO reflexes are observed when carbon material is homogeneously dispersed in the composite21,26. Broad reflexes for both samples indicate a small size of ammonium vanadate crystals, which is in agreement with further SEM observations. Raman spectroscopy analysis was performed to identify the characteristic bonds of NH4V4O10 as well as to confirm the presence of rGO in the composite (Fig. 1b). The bands observed in the low wavenumber region (< 1000 cm-1) are associated with V–O bonds and are similar to those reported for NH4V4O1027. The band at 147 cm-1 is due to the layered structure of NH4V4O10 and bending vibration of (V2O2)n chains28. The band at 285 cm-1 originates from the bending vibration of O-V = O28. The symmetric and antisymmetric stretching modes of V–O-V appear at 540 cm-1 and 720 cm-1, respectively, while the bending mode appears at 450 cm-129. In the NVO/rGO spectrum, two new distinct modes located at 1351 cm-1 and 1616 cm-1 are the D and G bands, which are characteristic of graphene-based materials and prove the presence of rGO. The G band arises from the in-planar stretching of symmetric sp2 C–C bonds in graphite-derived carbon materials. The D band is attributed to the presence of interruptions that occurred in the symmetric hexagonal graphitic lattice, such as heptagon and pentagon rings, edge defects, and functional groups. Such disruptions are typical for rGO and are beneficial for composite preparation, as the folding of the defective graphene sheets facilitates the homogeneous distribution of the material in the final structure. The characteristic bonds of NH4V4O10 and rGO were further confirmed by FTIR analysis (Fig. S1). The spectrum of pristine NVO contains a few pronounced bands associated with the vibrations of V–O bonds: symmetric and asymmetric stretching of V–O-V (535 cm-1 and 740 cm-1) and symmetric stretching of V = O (980 cm-1)30. The observed splitting of the V = O band indicates the existence of V5+ and V4+ in the structure and is typical for NH4V4O10, which belongs to the mixed-valence vanadium compounds28. Absorption bands at 1405 cm-1 and 3180 cm-1 correspond to the bending and stretching modes of N–H in NH4+, respectively31. Bands located at 1630 cm-1 and 3450 cm-1 can be assigned to the O–H bending and stretching vibrations of adsorbed water. In the NVO/rGO spectrum, a new band located at 1560 cm-1 can be clearly observed, which corresponds to the C = C skeleton vibration of the graphene sheet 32. In addition, weak bands associated with carbon‒oxygen bonds can also be observed for NVO/rGO. This implies that after the hydrothermal reaction, some oxygen functionalities are still present on the surface of the graphene sheets. Such residual groups are a typical feature of rGO and are beneficial for attracting dye molecules33 and metal ions.

Structural analysis of NVO and NVO/rGO: (a) XRD, (b) Raman, (c) TG (air, 10 °C/min), (d,e) V 2p XPS spectra and (f) V K-edge XANES spectra (the inset shows the relation between the vanadium oxidation state and the edge position).

The content of various components within the vanadate/rGO composites can be estimated by TGA under an air atmosphere. Calculations are based on the difference in mass loss between pure ammonium vanadate and its composites with rGO22,34. As shown in Fig. 1c, the total mass loss for pure NVO up to 600 °C is 5.5%, and two main regions can be distinguished, which correspond to the removal of adsorbed water (before 110 °C) and ammonium groups (110–370 °C) by the release of ammonia and water. The 4.9% loss in the second region indicates the absence of crystal water, and its value agreed well with the molar mass of the ammonium group in the nonhydrated NH4V4O10 phase. Compared to NVO, NVO/rGO reveals an additional sharp mass loss (12.9%) with a maximum ca. 410 °C, which is attributed to the combustion of rGO sheets in the composite 22. Moreover, the mass loss in the range of 110–370 °C is doubled. This is caused by the decomposition of residual oxygen-containing groups of rGO. Considering the differences in the total mass loss between both samples, the content of rGO in the NVO/rGO composite was calculated to be equal to 18.9%. To investigate the surface oxidation state of V in the studied samples, XPS analysis was carried out. The high-resolution XPS spectra of the V 2p region (Fig. 1d,e) reveal two peaks located at 524.5 eV and 517.3 eV assigned to the V 2p1/2 and V 2p3/2 doublets. The observed asymmetry of the peaks indicates the coexistence of V5+ and V4+ and confirms the mixed-valence nature of the obtained samples. Thus, for further analysis, V 2p3/2 was deconvoluted for two peaks at 517.6 eV and 516.2 eV corresponding to V5+ and V4+, respectively. According to the fitted peak areas, the ratio of V5+/V4+ in both samples is similar and equal to 1.6, which is almost two times lower than the theoretical value for NH4V4O10. Taking into account the stoichiometry of NH4V4O10, the theoretical content of V5+ is 75%, while that of V4+ is 25%. At the same time, it should be kept in mind that XPS is a surface-sensitive method, and the obtained results indicate a high content of V4+ (39%) on the surface, which may be different in the bulk. Furthermore, the valence state of vanadium in the bulk determined from XAS analysis was 4.75. As shown in Fig. 1f, the edge position for NVO/rGO lies between the energies of the V2O5 and V2O references. It should be noted that transmission mode XAS analysis refers to the bulk oxidation state, while XPS is a surface-sensitive method. It is known from the literature that V4+ species can be generated on the surface of vanadates during their synthesis35,36. It was also proven that the presence of surface V4+ species is also beneficial for the photocatalytic process and will be discussed later.

The morphology of the prepared samples was investigated using SEM. As shown in Fig. 2a,c), NVO exhibits a flower-like microstructure with an average diameter size equal to 10 µm. The observed structures are built of nanobelts with a length of 2–7 µm and a width of 500 nm. The thickness of the nanobelt is approximately 40 nm. By comparison, the NVO/rGO sample possesses a very different morphology. As seen in Fig. 2b,d), the composite is characterized by a porous structure made of connected nanobelts, which are wrapped with rGO sheets. The width of the nanobelts is smaller than that for NVO and equal to 200 nm, which can be attributed to the slower growth rate limited by rGO. Such a unique structure should facilitate the migration of aqueous solution, ensuring better contact of pollutants with active sites when used as a photocatalyst material for water treatment. It is also expected that the hierarchically organized structure of the NVO/rGO composite ensures its stability, which will improve the reusability of photocatalysts. Figure S2 shows the N2 adsorption–desorption isotherms of NVO and NVO/rGO. Both samples exhibit a type-IV isotherm with a hysteresis loop typical for mesoporous materials. It is known that the existence of mesopores in the photocatalyst facilitates the accessibility of pollutant molecules, enhancing its effectiveness37. The pore size distribution, calculated with the BJH model, reveals that for both samples, the pore radius is in the range of 2–40 nm. NVO possesses mostly small pores with a mean radius size equal to 2 nm, while NVO/rGO is characterized by a bimodal size distribution with pore radii centered at 2 nm and 8 nm. The cumulative pore volume of NVO/rGO (0.19 cm3/g) was more than two times larger than that of NVO (0.08 cm3/g). In addition, the specific surface area was determined to be 28 m2/g and 33 m2/g for NVO and NVO/rGO, respectively. As expected, the composite shows a larger surface area, owing to the high intrinsic surface area of rGO and the self-organized porous structure of NVO/rGO. The high-resolution TEM images of NVO (Fig. 2e) and NVO/rGO (Fig. 2f) show that the lattice plane is 0.96 nm and corresponds to the characteristic (001) plane of NH4V4O10, as observed from the XRD pattern (shown in Fig. 1a).

SEM images of NVO (a,c) and NVO/rGO (b,d) and (e,f) high-resolution TEM images of NVO and NVO/rGO, respectively.

Diffuse reflectance UV‒Vis spectroscopy was applied to study the optical properties of both materials. The band gap energies were calculated using the Kubelka–Munk method based on the diffuse reflectance spectra presented in Fig. 3a. The Kubelka–Munk model is the basis for determining the band gap of thick, optically rough powder samples. Following38, (f(KM)∙hν)1/n (for n = 1/2 assuming a direct bandgap) was plotted as a function of the incident photon energy (hν), and the results are depicted in Fig. 3b,c for NVO and NVO/rGO, respectively. The band gap of both materials was determined by extrapolation of the linear region of (f(KM)∙hv)2 vs hv to y = 0. The intersection point of the extrapolated line with the abscissa gives the value of Eg. As shown in Fig. 3b, the obtained energy band gap for NVO is 2.28 eV, which is in good agreement with the previously published value39,40. The optical band gap of NVO/rGO was determined to be 1.5 eV. The reported values for rGO cover a wide range between 0.02 and ca. 2 eV41,42,43, but the Eg of rGO is generally lower than that of NVO; thus, the bandgap narrowing in a synthesized composite is not surprising. The band gap decrease upon adding rGO to known photocatalysts, such as ZnO or TiO2, was also reported in the literature44,45. The positive influence of rGO on photocatalytic activity has been recently reviewed by Mondal et al.46. The results obtained by us are in line with the worldwide trends summarized in this review.

Optical properties of NVO and NVO/rGO: Reflectance spectra (a) and the (f(KM)·hν)2 vs hν plots resulting from the UV‒Vis reflectance spectra with corresponding energy band gaps for NVO (b) and NVO/rGO (c).

The photoemission spectra of the samples were measured using UV radiation as the excitation source. The results are shown in Figure S3. The intensity of emission is very low for both NVO and NVO/rGO. Nevertheless, a band at approximately 460 nm was registered. Similar behaviour was already observed for K-containing vanadate—K2V6O16·0.65H2O19. Taking into account that the energy band gap estimated from the UV‒vis spectrum equals approximately 2.28 eV (~ 543 nm), the observed emission band is not related to the conduction to valence band transition. The emission band with a maximum at 460 nm was reported for V2O5 nanostructures and was associated with recombination of electrons photoexcited to higher than conduction band edge levels47. Here, despite the very low intensity of emission, it can be seen that the presence of rGO in the composite quenches the photoluminescence significantly. It is often an indication that recombination is hindered due to the transfer of photoexcited electrons to rGO, and the separation of charge carriers that can participate in photocatalytic processes is improved. The comparison of EIS spectra recorded at rest potential is shown in Fig. 4a. As expected, the presence of highly conductive rGO affects the electrical properties of the material. The resistance of charge transfer, seen as the diameter of the semicircle on the spectra, is evidently diminished, suggesting that the conductivity of the sample is enhanced due to the presence of rGO. To compare the electrochemical activity of both materials using the cyclic voltammetry technique, see Figure S4. In the case of bare NVO, reversible redox activity, probably associated with the electrochemical activity of surface V-containing groups, was registered. Additionally, the cathodic current can be seen at a potential lower than approximately 0 V vs Ag/AgCl (3 M KCl), which can be related to the conduction band level. Such a shape is characteristic of n-type semiconductors because n-type semiconductors can act as cathodes for both illuminated and dark conditions48. The CV curve of NVO/rGO is much more complex and contains 4 electrochemical activities in the measured potential range. Additionally, the measured current is much higher than that for NVO. Despite the fact that both materials differ from each other by the presence of rGO, the additional electroactivities do not originate from the rGO49. Their presence is related to the better electrical properties of the investigated electrode material and facilitated electrochemical activity of NVO. Mott-Schottky analysis was performed to estimate the flat-band potential of NVO (see Fig. 4b). The slope of the 1/Csc2 is positive, confirming that NVO is n-type semiconductor. Some frequency dispersion was observed; however, it can be concluded that the flat-band potential is approximately -0.1 V vs Ag/AgCl (3 M KCl) (0.52 V vs NHE). Notably, the estimated value is close to the maximum of the cathodic peak seen on the CV curve, which is consistent and characteristic with the n-type conductivity (the conduction band edge and flat-band potential are close to each other).

(a) Typical Nyquist plots recorded for NVO/RGO and NVO at rest potential equals to about 0.3 V and (b) the cyclic voltammetry curve of NVO, recorded in 0.2 M K2SO4, scan rate: 50 mV/s and Mott–Schottky plot of NVO electrode at different frequencies.

The photocatalytic activity of the prepared samples was first evaluated by the degradation of the organic dye methylene blue (MB) under simulated sunlight. Before the photocatalysis experiments, the adsorption of MB on the surface of the tested powders was evaluated under dark conditions (Figure S5a). Adsorption–desorption equilibrium was achieved after ca. 30 min for both samples, and approximately 20% of the dye was adsorbed. The observed good adsorption ability comes from the high specific surface area of the tested materials (confirmed by BET) and is essential for the photocatalysis process, ensuring improved contact between the pollutant molecules and reaction active sites50,51. Figure 5 presents the results of the photocatalytic performance of NVO and NVO/rGO toward MB degradation. An illuminated MB solution without the addition of photocatalysts (blank) was also added for comparison and revealed a negligible photolysis effect. Similarly, the photocatalytic performance of pure rGO was measured as a control experiment and is presented in Figure S5b. After 60 min of illumination, NVO degraded 82% of MB. To the best of our knowledge, only three publications devoted to the usage of NH4V4O10 in photocatalytic applications have been reported. For example, the experiments conducted by Aboood et al. reveal that the cross-like NH4V4O10 nanobelt arrays do not show any catalytic action for the degradation of rhodamine B after 210 min under visible light52. However, scientists have shown that photoactivity can be induced by calcination (above 400 °C) of the as-obtained structures and their transformation to V2O5. Two other works are devoted to the heterojunction of NH4V4O10 with quantum dots (CdS and C-dots). Y. Zhang et al. designed an efficient ternary C-dots/SrTiO3/NH4V4O10 catalyst for the removal of sulfamethoxazole, aureomycin hydrochloride, and ciprofloxacin residues in aqueous samples26. The reported photocatalytic degradation efficiency of the antibiotics for pure NH4V4O10 was lower than 20%, which was 4–5 times lower than that for the heterojunction. S. Le prepared an intercalated CdS/NH4V4O10 composite that degraded 90% of amoxicillin within 120 min under simulated sunlight, while pure NH4V4O10 can degrade 50%. Taking into consideration the above examples, the photocatalytic efficiency obtained in this work for pure NH4V4O10 is unexpectedly high. It is suggested that the excellent photoactivity of NVO results from the high content of V4+ on the surface and well-developed surface area. It has been demonstrated that V4+ can trap photogenerated electrons and promote efficient charge separation, enhancing photocatalytic performance in water splitting and degradation of pollutants35,53,54. It has also been reported that the existence of V4+ can lead to the formation of intermediate defect energy states and the widening of the optical absorption range55. V4+ species can be introduced into the structure of various vanadates in several different ways, such as doping with other elements54, post-treatment (e.g., calcination56, plasma modification53) or hydrothermal reduction with reducing additives35. The last approach was also used in this study, and oxalic acid was added during the synthesis. As confirmed by physicochemical characterization, oxalic acid serves as a reductant and induces the formation of V4+ on the surface of NH4V4O10 during the hydrothermal process. It should also be noted that oxalic acid can act as a forming agent during the hydrothermal synthesis of ammonium vanadates22. Thus, it is suggested that its addition led to the formation of 3D flower-like microstructures, as observed here for bare NH4V4O10.

Photocatalytic degradation of MB under simulated solar light: (a) C/C0 vs t plot and (b,c) active species trapping experiments with the addition of BQ, AO, and TBA as scavengers for O2- radicals, holes h + , and hydroxyl radicals ·OH, respectively.

Moreover, herein, we propose to combine NH4V4O10 with rGO. This can be done during a hydrothermal reaction, which in contrast to the synthesis of previously mentioned heterojunctions is a one-step process. Another advantage of such synthesis is a hierarchal porous structure that is formed during the hydrothermal reaction. In contrast to the NVO sample, in the case of the NVO/rGO composite, the morphology is probably affected by both oxalic acid and graphene oxide. As shown in Fig. 5, the coupling of NH4V4O10 with rGO resulted in improved photocatalytic performance, which reached 92% within 60 min.

The kinetics of MB photodegradation were further studied by plotting -ln(C/C0) as a function of irradiation time (Figure S6). In the case of NVO, the is most likely pseudo-first-order kinetics according to the Langmuir–Hinshelwood model, and the calculated rate constant k was equal to 0.0251 min-1. For NVO/rGO, the mechanism of MB photodegradation can be more complex (as indicated by the low linear regression coefficient); however, it can be clearly seen that at the beginning of illumination, the process is much faster. To identify the main reactive species involved in the photodegradation process, further tests were performed in the presence of different scavengers. Benzoquinone (BQ), ammonium oxalate (AO), and tert-butyl alcohol (TBA) were used as scavengers for ·O2- radicals, holes h + , and hydroxyl radicals ·OH, respectively. As depicted in Fig. 5b-c), compared with the photocatalytic process without scavengers, the removal rate of MB by NVO decreased by 47% and 29% in the presence of TBA and AO, while no change was observed with the addition of BQ. This indicates that ·OH and h + play a critical role in MB photodegradation. In contrast, the degradation of MB with the composite is highly suppressed by BQ, indicating the main role of ·O2- radicals in the process. The addition of AO and TBA also shows a significant inhibitory effect, which indicates that h + and ·OH also contribute to the degradation of MB. The reusability of NVO and NVO/rGO was further investigated by performing 4 consecutive photodegradation cycles for MB (Fig. 6). The results revealed that the activity of NVO gradually decreases, and in the 4th cycle, the efficiency drops to 56%. Better stability was observed in the case of the composite. The results obtained for NVO/rGO show that the degradation efficiency was maintained at a good level during each reaction cycle during irradiation, and consequently, the photocatalyst could be reused.

Reusability of the NVO (a) and NVO/rGO (b) photocatalysts for the degradation of MB.

The obtained photocatalysts were also used in the Cr(VI) photoreduction process at pH 3. It is well known that under acidic conditions, Cr(VI) is mainly present in the form of HCrO4− or Cr2O72−, which eventually promotes the reduction of Cr(VI) to Cr(III)57. As in the case of the photodegradation of MB, the composite was characterized by a better reduction efficiency of the chromium compound. The adsorption–desorption equilibrium was attained for 30 min in the dark. The results are presented in Fig. 7a.

The photocatalytic reduction of Cr(VI) to Cr(III) under simulated solar light: (a) C/C0 vs t plot and (b) reusability of NVO/rGO.

The decrease in Cr(VI) concentration due to dark adsorption as well as during illumination was higher for the composite. The greatest decrease in Cr(VI) concentration in the case of NVO/rGO was observed in the first 15 min of illumination, and then the performance of the catalyst slowly stopped. As a result, after one hour of exposure, the photoreduction amounted to approximately 70% (in the case of NVO, only 20%). The modified material, namely, NVO/rGO, showed a greater ability to degrade the hazardous chromium form, which was due to the presence of rGO, which was responsible for more efficient separation and prolonged recombination time of electron–hole pairs. Moreover, as shown in Fig. 7b, the NVO/rGO composite displays good reusability and after four consecutive cycles, the degradation efficiency of Cr(VI) slightly decreases to 65%. The above experimental results demonstrate the great potential of the obtained NVO and NVO/rGO in the photodegradation of water pollutants. In contrast to the previous study52, it was shown that pristine NH4V4O10 can be efficiently used for the degradation of organic dyes. Moreover, the proposed combination of NH4V4O10 with rGO not only increases the photocatalytic degradation reaction rate and improves the cyclic stability of photocatalyst but also widens its application, allowing for the efficient photoreduction of toxic Cr(VI). In comparison to other vanadium-based photocatalysts reported in the literature19,58,59,60,61,62,63,64,65 (Tables S1 and S2), NVO and NVO/rGO present better or similar efficiency towards the photodegradation of MB and Cr(VI). Importantly, proposed photocatalysts can be activated under solar light and exhibit significant photocatalytic degradation of pollutants within the first 60 min of illumination. Such an efficient and fast process, together with facile synthesis (one-step reaction, low-cost precursors) and good cyclic stability of NVO and NVO/rGO make them promising materials for solar-driven water purification.

Therefore, Ecb and Evb were calculated to be 0.75 eV and 3.03 eV, respectively. On the basis of the obtained results, a possible mechanism for the photocatalytic performance of NVO and NVO/rGO has been proposed and is schematically presented in Fig. 8.

Schematic diagram of the band-energy levels of NVO/rGO with the possible photocatalytic mechanism.

When NVO or NVO/rGO is exposed to solar illumination, NH4V4O10 becomes excited, and electron–hole pairs are generated. The photogenerated holes in the VB of NH4V4O10 can oxidize MB directly or react with water to produce (·OH), which are also able to indirectly oxidize organic species. At the same time, the Ecb of NH4V4O10 is lower than the reduction potential of O2 to ·O2- (-0.33 eV)66. However, in the case of the NVO/rGO composite, the photogenerated electrons can migrate from NH4V4O10 to rGO 67,68. It is known that the electrons at the reduced graphene oxide surface react readily with oxygen molecules and generate superoxide radical anions (·O2-) 67, which subsequently degrade the MB dye molecules. According to the results obtained from the active species trapping experiment, this process was the most dominant in NVO/rGO. On the other hand, the potential of the conduction band is more negative than the redox potential of the Cr2O72−/Cr3+ couple (1.33 eV vs NHE), which indicates that NH4V4O10 can reduce Cr(VI) ions using their photoexcited electrons. The efficiency of Cr(VI) photoreduction for NVO equals only 20% after 60 min of illumination, while for NVO/rGO, it reaches 70%. The improved photocatalytic performance originates from the unique structure of the NVO/rGO composite, in particular the existence of rGO, which acts as an electron acceptor and inhibits the recombination of electrons and holes. In addition, the NVO/rGO composite is characterized by a narrower band gap and higher adsorption capacity of Cr(VI) than NVO.

A one-pot hydrothermal method was successfully used to obtain NH4V4O10 (NVO) and its composite with rGO (NVO/rGO). The photocatalytic activity of synthesized NVO and NVO/rGO was evaluated towards methylene blue (MB) degradation and Cr(VI) to Cr(III) reduction under simulated solar light illumination. Excellent performance in MB photodegradation was obtained for both studied materials, which was attributed to the high content of V4+ surface species revealed by XPS studies, as well as the developed surface area of the photocatalysts. The positive impact of rGO in terms of the activity and stability of the photocatalyst was especially pronounced. Reactions carried out in the presence of specific scavengers revealed differences in the mechanism of photocatalyst action. In the case of NVO, ·OH and h + play a critical role in MB photodegradation, while for NVO/rGO, ·O2- radicals are the dominant active species responsible for dye degradation. Moreover, the proposed composite showed activity in the photoreduction of highly toxic Cr(VI) ions in an acidic environment and is therefore a promising photocatalyst for wastewater treatment containing both organic and inorganic contaminants. The hydrothermal synthesis parameters of NVO/rGO can cause different morphologies, particle sizes and crystallizations, resulting in different photocatalytic activities; therefore, such studies are planned to be carried out in our laboratory.

Ammonium metavanadate (NH4VO3, 99.0%), oxalic acid dihydrate (C2H2O4 × 2H2O, 97.0%), and methylene blue (MB > 98%) were obtained from Sigma‒Aldrich and used without further purification. Deionized water was used in all experiments (conductivity < 0,06 μS/cm). Graphene oxide (GO) employed in the composite synthesis was prepared using the modified Hummers method 69. Potassium dichromate (K2Cr2O7, ≥ 99.0%) and ammonium oxalate (AO, ≥ 99%) were purchased from Merck. Benzoquinone (BQ, > 98%) and tert-butyl alcohol (TBA, > 99.5%) were received from CheMondis.

The NH4V4O10/rGO (NVO/rGO) photocatalyst was prepared via a facile one-pot hydrothermal method. NH4VO3 and GO were used as precursors and mixed with a weight ratio of 10:1. In brief, 0.6 g of NH4VO3 and 0.6 g of oxalic acid were dissolved in 90 ml of deionized water. In the meantime, 60 mg of GO was dispersed in 30 ml of deionized water with ultrasonication (20 W, 30 min). Next, the prepared reagents were mixed together and sonicated for 15 min. Then, the as-obtained reaction mixture was transferred to a Teflon-lined stainless-steel autoclave (volume 1.8 L) for 8 h and 180 °C. Finally, the obtained product was washed with deionized water and dried at 40 °C under reduced pressure (0.01 bar). For comparison, bare NH4V4O10 (NVO) without GO was synthesized in an analogous procedure.

The crystal structure and phase composition of the samples were examined using powder X-ray diffraction (XRD, BrukerD2 Phaser diffractometer) with Cu Kα radiation (λ = 1.5404 Å). Raman spectra were acquired using a confocal micro-Raman system (Horiba Jobin Yvon) with a 632.8 nm laser excitation wavelength. Fourier transform infrared (FTIR) analysis was carried out on a Perkin Elmer Frontier spectrophotometer in the range of 500–4000 cm−1. Measurements were made in transmittance mode, and the potassium bromide pellet method was used. The valence state of vanadium was analysed using X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XPS). The high-resolution V 2p XPS spectra were collected on an Escalab 250Xi device (Thermo Fisher Scientific) equipped with a monochromatic AlKα source. Measurements were carried out at a 25 eV pass energy with a 0.1 eV energy step. The X-ray spot size was 250 µm. The calibration of the XPS spectrum was performed using the characteristic C1s peak at 284.6 eV. XAS analysis was performed at the ASTRA beamline at SOLARIS National Synchrotron Radiation Centre, Cracow, Poland. The V K-edge XANES of powder samples was obtained in transmission mode in the range of 5265 to 5550 eV. V2O3, VO2, and V2O5 were used as reference materials for the V(III), V(IV) and V(V) oxidation states. Thermogravimetric analysis (TGA) was conducted under air using a Netzsch STA 449 F1 at 10 °C/min from 40 °C to 600 °C. The morphology of the samples was investigated using scanning electron microscopy (SEM, ESEM Quanta Feg 250) and transition electron microscopy (TEM, FEI TECNAI G2 F20). N2 adsorption–desorption isotherms were measured on a NOVAtouch™ 2 surface analyser, and the Brunauer‒Emmett‒Teller (BET) method was used to calculate the specific surface area (relative pressure range p/p0: 0.1 to 0.3). The correlation coefficient of the linear regression was not less than 0.999. The pore size distribution and cumulative pore volume were evaluated using the BJH (Barrett, Joyner and Halenda) method from the desorption branch. The UV‒vis reflectance spectra of the selected materials were measured with a UV‒vis spectrophotometer (Lambda 35, Perkin-Elmer) equipped with a diffuse reflectance accessory. The spectra were registered in the range of 300–900 nm, with a scanning speed of 120 nm min−1. Band gap energy values were determined as the intercept of the x-axis of the plot of transformation of the Kubelka–Munk function. To determine the energy band gap (Ebg) of the chosen powders, the Kubelka–Munk function was applied:

where R –reflectance. The bandgap was estimated by extrapolation of the linear region of (f(KM) hν)n vs hν to y = 0. The power of n equals 2, assuming a direct band gap.

The PL spectra were measured using SCINCO FluoroMate FS-2 fluorescence spectrometer (excitation wavelength: 375 nm). Electrochemical measurements were accomplished using an Ivium Vertex potentiostat/galvanostat and a three-electrode cell with Pt mesh as the counter electrode and Ag/AgCl (3 M KCl) as the reference electrode. To perform these measurements, aqueous suspensions of NVO and NVO/rGO were drop-cast on glassy carbon disc electrodes. After drying with a hot stream of air, electrodes were tested in aqueous 0.2 M Na2SO4 solution. The EIS response was measured for 3 frequencies (500, 750, and 1000 Hz). The capacitance was estimated from the single points using the Csc = -1/ωZ″ formula (ω – angular frequency, Z’’ – imagine part of impedance).

The photocatalytic behaviour was investigated by the oxidation of methylene blue and reduction of Cr(VI). The photocatalytic performance was evaluated under simulated solar light using a 300 W Xe lamp (a high-pressure 150 W xenon lamp, LOT – QuantumDesign GmbH equipped with the AM1.5G filter). The intensity of the incident light that reaches the surface of the investigated solution was equal to 100 mWcm−2 (measured using a Coherentâ FieldMate Laser Power Meter). In a typical test, 20 mg of catalyst was placed in a 50 mL aqueous pollutant solution. The concentration of MB and Cr(VI) was 1·10–5 M. Before irradiation, the suspension was vigorously stirred in the dark for 30 min to reach desorption-adsorption equilibrium. The change in MB and Cr(VI) concentration was monitored by its absorption at 665 nm and 351 nm, respectively, from the UV–Vis (Spektrofotometr UV5100) spectra of the solution, using distilled water as a reference. A total of 0.75 ml of suspension was collected and centrifuged before UV‒Vis measurement. In the case of Cr(VI) photoreduction, the process was conducted in acidified (pH = 3) solutions.

To study the reusability of the prepared photocatalysts, the cycle experiment was repeated 4 times for the photodegradation of methylene blue. After each photodegradation test, the catalyst was collected by centrifugation, dried under natural conditions and used for the next degradation experiment. Moreover, to indicate the role of hydroxyl radicals (·OH), (h +) holes and superoxide radicals (·O2-) in the process of MB degradation, experiments were performed in the presence of appropriate scavengers: t-butanol (TBA), ammonium oxalate (AO) and benzoquinone (BQ). The concentration of each scavenger was equal to 1 mM.

All data generated or analysed during this study are included in this published article (and its Supplementary Information files).

Thirunavukkarasu, A., Nithya, R. & Sivashankar, R. A review on the role of nanomaterials in the removal of organic pollutants from wastewater. Rev. Environ. Sci. Biotechnol. 19, 751–778 (2020).

Article CAS Google Scholar

Saini, R. D. Textile organic dyes: Polluting effects and elimination methods from textile waste water. Int. J. Chem. Eng. Res. 9, 975–6442 (2017).

Google Scholar

Fernández, C., Larrechi, M. S. & Callao, M. P. An analytical overview of processes for removing organic dyes from wastewater effluents. TrAC–Trends Analyt. Chem. 29, 1202–1211 (2010).

Article Google Scholar

Zamora-Ledezma, C. et al. Heavy metal water pollution: A fresh look about hazards, novel and conventional remediation methods. Environ. Technol. Innov. 22, 101504 (2021).

Article CAS Google Scholar

Fato, F. P., Li, D. W., Zhao, L. J., Qiu, K. & Long, Y. T. Simultaneous removal of multiple heavy metal ions from river water using ultrafine mesoporous magnetite nanoparticles. ACS Omega 4, 7543–7549 (2019).

Article CAS PubMed Central PubMed Google Scholar

Xu, B., Dong, J., Wang, X. & Yao, Y. Monitoring Cr(VI) photoreduction at different depths by operando low-field NMR relaxometry. Magnet. Resonance Lett. 2, 170–176 (2022).

Article CAS Google Scholar

Kinuthia, G. K. et al. Levels of heavy metals in wastewater and soil samples from open drainage channels in Nairobi, Kenya: Community health implication. Sci. Rep. 10, 1–13 (2020).

Google Scholar

Kamble, G. S. & Ling, Y. C. Solvothermal synthesis of facet-dependent BiVO4 photocatalyst with enhanced visible-light-driven photocatalytic degradation of organic pollutant: Assessment of toxicity by zebrafish embryo. Sci. Rep. 10, 1–11 (2020).

Article Google Scholar

Rajaitha, P. M. et al. Unraveling highly efficient nanomaterial photocatalyst for pollutant removal: A comprehensive review and future progress. Mater. Today Chem. 23, 100692 (2022).

Article CAS Google Scholar

Singh, V. et al. Highly functionalized photo-activated metal–organic frameworks for dye degradation: Recent advancements. Materialstoday Commun. 34, 105180 (2023).

CAS Google Scholar

Gautam, S. et al. Metal oxides and metal organic frameworks for the photocatalytic degradation: A review. J Environ Chem Eng 8, 103723 (2020).

Article Google Scholar

He, H., Luo, Z., Tang, Z. Y. & Yu, C. Controllable construction of ZnWO4 nanostructure with enhanced performance for photosensitized Cr(VI) reduction. Appl. Surf. Sci. 490, 460 (2019).

Article CAS ADS Google Scholar

Samsudin, M. F. R., Sufian, S. & Hameed, B. H. Epigrammatic progress and perspective on the photocatalytic properties of BiVO4-based photocatalyst in photocatalytic water treatment technology: A review. J. Mol. Liq. 268, 438–459 (2018).

Article CAS Google Scholar

Lotfi, S., Ouardi, M. E., Ahsaine, H. A. & Assani, A. Recent progress on the synthesis, morphology and photocatalytic dye degradation of BiVO4 photocatalysts: A review. Catal. Rev. Sci. Eng. 00, 1–45 (2022).

Article CAS Google Scholar

Hassan, A., Iqbal, T., Tahir, M. B. & Afsheen, S. A review on copper vanadate-based nanostructures for photocatalysis energy production. Int. J. Energy Res. 43, 9–28 (2019).

Article CAS Google Scholar

Guo, J. et al. Efficient visible-light driven photocatalyst, silver (meta)vanadate: Synthesis, morphology and modification. Chem. Eng. J. 352, 782–802 (2018).

Article CAS Google Scholar

Yanga, R. et al. InVO4-based photocatalysts for energy and environmental applications. Chem. Eng. J. 428, 131145 (2022).

Article Google Scholar

Trzciński, K., Szkoda, M., Sawczak, M., Karczewski, J. & Lisowska-Oleksiak, A. Visible light activity of pulsed layer deposited BiVO 4 /MnO 2 films decorated with gold nanoparticles: The evidence for hydroxyl radicals formation. Appl. Surf. Sci. 385, 199–208 (2016).

Article ADS Google Scholar

Nadolska, M. et al. Insight into potassium vanadates as visible-light-driven photocatalysts: Synthesis of V(IV)-rich nano/microstructures for the photodegradation of methylene blue. Inorg. Chem. 61, 9433–9444 (2022).

Article CAS PubMed Central PubMed Google Scholar

Le, T. K., Kang, M., Tran, V. T. & Kim, S. W. Relation of photoluminescence and sunlight photocatalytic activities of pure V2O5 nanohollows and V2O5/RGO nanocomposites. Mater. Sci. Semicond. Process. 100, 159–166 (2019).

Article CAS Google Scholar

Li, C. et al. NH4V4O10/rGO Composite as a high-performance electrode material for hybrid capacitive deionization. Environ. Sci. (Camb) 6, 303–311 (2020).

CAS Google Scholar

Cui, F. et al. Deficiency and surface engineering boosting electronic and ionic kinetics in NH4V4O10 for high-performance aqueous zinc-ion battery. Energy Storage Mater 44, 197–205 (2022).

Article Google Scholar

Wang, H. et al. Mo-doped NH4V4O10 with enhanced electrochemical performance in aqueous Zn-ion batteries. J. Alloys Compd. 858, 15830 (2021).

Article Google Scholar

Chen, Q., Xia, Q., Xu, Y., Wang, P. & Tan, Q. NH 4 V 4 O 10 micro-flowers as cathode material for high performance hybrid magnesium-lithium-ion batteries. Mater. Lett. 247, 178–181 (2019).

Article CAS Google Scholar

Esparcia, E. A., Chae, M. S., Ocon, J. D. & Hong, S. T. Ammonium vanadium bronze (NH4V4O10) as a high-capacity cathode material for nonaqueous magnesium-ion batteries. Chem. Mater. 30, 3690–3696 (2018).

Article CAS Google Scholar

Zhang, Y., Li, Y., Yuan, Y. & Lin, K. C-dots decorated SrTiO3/NH4V4O10 Z-scheme heterojunction for sustainable antibiotics removal: Reaction kinetics, DFT calculation and mechanism insight. Sep. Purif. Technol. 295, 121268 (2022).

Article CAS Google Scholar

Fang, D. et al. Novel hierarchical three-dimensional ammonium vanadate nanowires electrodes for lithium ion battery. Appl. Surf. Sci. 360, 658–665 (2016).

Article CAS ADS Google Scholar

Zhang, H. et al. Layered ammonium vanadate nanobelt as efficient adsorbents for removal of Sr2+ and Cs+ from contaminated water. J. Colloid. Interface Sci. 615, 110–123 (2022).

Article CAS ADS PubMed Google Scholar

Frost, R. L., Erickson, K. L., Weier, M. L. & Carmody, O. Raman and infrared spectroscopy of selected vanadates. Spectrochim. Acta A Mol. Biomol. Spectrosc. 61, 829–834 (2005).

Article ADS PubMed Google Scholar

Sarkar, S., Veluri, P. S. & Mitra, S. Morphology controlled synthesis of layered NH4V 4O10 and the impact of binder on stable high rate electrochemical performance. Electrochim. Acta 132, 448–456 (2014).

Article CAS Google Scholar

Prześniak-Welenc, M., Nadolska, M., Nowak, A. P. & Sadowska, K. Pressure in charge. Neglected parameter in hydrothermal synthesis turns out to be crucial for electrochemical properties of ammonium vanadates. Electrochim Acta, 339, 0–8 (2020).

Ţucureanu, V., Matei, A. & Avram, A. M. FTIR spectroscopy for carbon family study. Crit. Rev. Anal. Chem. 46, 502–520 (2016).

Article PubMed Google Scholar

Jahan, N. et al. A comparative study on sorption behavior of graphene oxide and reduced graphene oxide towards methylene blue. Case Stud. Chem. Environ. Eng. 6, 100239 (2022).

Article CAS Google Scholar

Kou, L., Wang, Y. & Song, J. Reduced graphene oxide nanosheets decorated carbon-coated NH4V3O8 as cathode materials with superior cycle stabilities for lithium-ion batteries. Appl. Phys. A Mater. Sci. Process 128, 1–8 (2022).

Article ADS Google Scholar

Zhang, Y. et al. Facile synthesis of V4+ self-doped, [010] oriented BiVO4 nanorods with highly efficient visible light-induced photocatalytic activity. Phys. Chem. Chem. Phys. 16, 24519–24526 (2014).

Article CAS PubMed Google Scholar

Song, H., Luo, M. & Wang, A. High rate and stable li-ion insertion in oxygen-deficient LiV3O8 nanosheets as a cathode material for lithium-ion battery. ACS Appl. Mater. Interfaces 9, 2875–2882 (2017).

Article CAS PubMed Google Scholar

Appavu, B., Thiripuranthagan, S., Ranganathan, S., Erusappan, E. & Kannan, K. BiVO4 /N-rGO nano composites as highly efficient visible active photocatalyst for the degradation of dyes and antibiotics in eco system. Ecotoxicol. Environ. Saf. 151, 118–126 (2018).

Article CAS PubMed Google Scholar

Landi, S. et al. Use and misuse of the Kubelka-Munk function to obtain the band gap energy from diffuse reflectance measurements. Solid State Commun. 341, 114573 (2022).

Article CAS Google Scholar

Le, S., Ma, Y., He, D., Wang, X. & Guo, Y. CdS/NH4V4O10 S-scheme photocatalyst for sustainable photo-decomposition of amoxicillin. Chem. Eng. J. 426, 130354 (2021).

Article CAS Google Scholar

Wang, H. et al. Mo-doped NH4V4O10 with enhanced electrochemical performance in aqueous Zn-ion batteries. J. Alloys Compd. 858, 158380 (2021).

Article CAS Google Scholar

Shen, Y. et al. Evolution of the band-gap and optical properties of graphene oxide with controllable reduction level. Carbon N. Y. 62, 157–164 (2013).

Article CAS Google Scholar

Zelechowska, K., Prześniak-Welenc, M., Łapiński, M., Kondratowicz, I. & Miruszewski, T. Fully scalable one-pot method for the production of phosphonic graphene derivatives. Beilstein J. Nanotechnol. 8, 1094–1103 (2017).

Article CAS PubMed Central PubMed Google Scholar

Jin, Y., Zheng, Y., Podkolzin, S. G. & Lee, W. Band gap of reduced graphene oxide tuned by controlling functional groups. J. Mater. Chem. C Mater. 8, 4885–4894 (2020).

Article CAS Google Scholar

Merazga, A. et al. Optical band-gap of reduced graphene oxide/TiO2 composite and performance of associated dye-sensitized solar cells. Mater. Sci. Eng. B Solid State Mater. Adv. Technol. 259, 145581 (2020).

Article Google Scholar

Mangavati, S. et al. Defects and band gap shrinkage in ZnO/rGO composite nano-pebbles prepared by solid–state reaction. Diam. Relat. Mater. 123, 108886 (2022).

Article CAS ADS Google Scholar

Mondal, A., Prabhakaran, A., Gupta, S. & Subramanian, V. R. Boosting photocatalytic activity using reduced graphene oxide (RGO)/semiconductor nanocomposites: Issues and future scope. ACS Omega 6, 8734–8743. https://doi.org/10.1021/acsomega.0c06045 (2021).

Article CAS PubMed Central PubMed Google Scholar

Le, T. K., Kang, M. & Kim, S. W. Morphology engineering, room-temperature photoluminescence behavior, and sunlight photocatalytic activity of V2O5 nanostructures. Mater. Charact. 153, 52 (2019).

Article CAS Google Scholar

Bott, A. W. Electrochemistry of semiconductors. Curr. Sep. 17, 87–91 (1998).

CAS Google Scholar

Chen, Y., Zhang, X., Zhang, D., Yu, P. & Ma, Y. High performance supercapacitors based on reduced graphene oxide in aqueous and ionic liquid electrolytes. Carbon N. Y. 49, 573 (2011).

Article CAS Google Scholar

Chen, J. et al. Insight into the synergistic effect of adsorption-photocatalysis for the removal of organic dye pollutants by Cr-doped ZnO. Langmuir 44, 520–533 (2020).

Article Google Scholar

Chang, L. et al. Excellent adsorption-photocatalysis synergistic activity of 3D–3D flower-like BiOBr/graphene hydrogel composite and the removal of potassium butyl xanthate. New J. Chem. 44, 2479–2488 (2020).

Article CAS ADS Google Scholar

Abbood, H. A., Peng, H., Gao, X., Tan, B. & Huang, K. Fabrication of cross-like NH4V4O10 nanobelt array controlled by CMC as soft template and photocatalytic activity of its calcinated product. Chem. Eng. J. 209, 245–254 (2012).

Article CAS Google Scholar

Che, G. et al. Solution plasma boosts facet-dependent photoactivity of decahedral BiVO4. Chem. Eng. J. 397, 125381 (2020).

Article CAS Google Scholar

Kong, D. et al. Ni-Doped BiVO4 with V4+ Species and Oxygen Vacancies for Efficient Photoelectrochemical Water Splitting. Transact. Tianjin Univ. 25, 340–347 (2019).

Article CAS Google Scholar

Chen, L. et al. In situ synthesis of V4+ and Ce3+ self-doped BiVO4/CeO2 heterostructured nanocomposites with high surface areas and enhanced visible-light photocatalytic activity. J. Phys. Chem. C 120, 18548–18559 (2016).

Article CAS Google Scholar

Saputera, W. H. et al. Photocatalytic degradation of palm oil mill effluent (Pome) waste using bivo4 based catalysts. Molecules 26, 6225 (2021).

Article CAS PubMed Central PubMed Google Scholar

Szkoda, M., Zarach, Z., Nadolska, M., Trykowski, G. & Trzciński, K. SnO2 nanoparticles embedded onto MoS2 nanoflakes–an efficient catalyst for photodegradation of methylene blue and photoreduction of hexavalent chromium. Electrochim. Acta 414, 140173 (2022).

Article CAS Google Scholar

Phanichphant, S., Nakaruk, A., Chansaenpak, K. & Channei, D. Evaluating the photocatalytic efficiency of the BiVO4/rGO photocatalyst. Sci. Rep. 9, 16091 (2019).

Article PubMed Central ADS PubMed Google Scholar

Bhardwaj, D., Sangwan, S., Shivashankar, S. A. & Umarji, A. M. Microwave-assisted synthesis of reduced graphene oxide/V2O5 nano-composite as an efficient photocatalyst for dye degradation. Bull. Mater. Sci. 45, 135 (2022).

Article CAS Google Scholar

Muhammad Salim Mansha, T. I. Experimental and theoretical study of novel rGO/AgVO3 nano-hetrostructures for their application as efficient photocatalyst. Opt. Mater. Amst. 131, 112591 (2022).

Article Google Scholar

Sajid, M. M. et al. Photocatalytic performance of ferric vanadate (FeVO4) nanoparticles synthesized by hydrothermal method. Mater. Sci. Semicond. Process 129, 105785 (2021).

Article CAS Google Scholar

Hu, J. et al. In situ preparation of Bi2S3nanoribbon-anchored BiVO4nanoscroll heterostructures for the catalysis of Cr(vi) photoreduction. Catal. Sci. Technol. 10, 3843 (2020).

Article CAS Google Scholar

Jia, J. et al. La3+, Gd3+-codoped BiVO4 nanorods with superior visible-light-driven photocatalytic performance for simultaneous removing aqueous Cr(VI) and azo dye. J. Nanopart. Res. 22, 1 (2020).

Article Google Scholar

Dadigala, R. et al. Fabrication of novel 1D/2D V2O5/g-C3N4 composites as Z-scheme photocatalysts for CR degradation and Cr (VI) reduction under sunlight irradiation. J. Environ. Chem. Eng. 7, 102822 (2019).

Article CAS Google Scholar

Li, C., Che, H., Yan, Y., Liu, C. & Dong, H. Z-scheme AgVO3/ZnIn2S4 photocatalysts: "One Stone and Two Birds" strategy to solve photocorrosion and improve the photocatalytic activity and stability. Chem. Eng. J. 398, 125523 (2020).

Article CAS Google Scholar

Santos, R. K. et al. Ag3PO4/NiO composites with enhanced photocatalytic activity under visible light. ACS Omega 5, 21651–21661 (2020).

Article CAS PubMed Central PubMed Google Scholar

Sajid, M. M. et al. Study of the interfacial charge transfer in bismuth vanadate/reduce graphene oxide (BiVO4/rGO) composite and evaluation of its photocatalytic activity. Res. Chem. Intermed. 46, 1201 (2020).

Article CAS Google Scholar

Zhang, L. et al. Synthesis of butterfly-like BiVO4/RGO nanocomposites and their photocatalytic activities. Chin. J. Chem. Eng. 26, 667 (2018).

Article CAS Google Scholar

Kondratowicz, I., Żelechowska, K., Nadolska, M., Jażdżewska, A. & Gazda, M. Comprehensive study on graphene hydrogels and aerogels synthesis and their ability of gold nanoparticles adsorption. Colloids Surf. A Physicochem. Eng. Asp. 528, 65–73 (2017).

Article CAS Google Scholar

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This work is supported by the National Science Center of Poland (Grant No. 2020/37/N/ST5/03697). The authors also acknowledge the financial support from Gdańsk University of Technology by the DEC- 39/2021/IDUB/I.3.3 grant under the Argentum—‘Excellence Initiative—Research University program. The authors would like to acknowledge Michał Maciejewski from Gdańsk University of Technology, Faculty of Applied Physics and Mathematics, for enabling the PL measurements.

Institute of Nanotechnology and Materials Engineering, and Advanced Materials Centre, Gdansk University of Technology, Narutowicza 11/12, 80-233, Gdansk, Poland

M. Nadolska, J. Ryl & M. Prześniak-Welenc

Faculty of Chemistry, Gdansk University of Technology, Narutowicza St. 11/12, 80-233, Gdansk, Poland

M. Szkoda & K. Trzciński

Institute of Experimental Physics, Faculty of Mathematics, Physics and Informatics, University of Gdańsk, Wita Stwosza 57, 80-308, Gdańsk, Poland

A. Lewkowicz

Nalecz Institute of Biocybernetics and Biomedical Engineering, Polish Academy of Sciences, Ks Trojdena 4, 02-109, Warsaw, Poland

K. Sadowska

Institute of High Pressure Physics, Polish Academy of Sciences, Sokołowska 29/37, 01-142, Warsaw, Poland

J. Smalc-Koziorowska

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Conceptualization: M.N., Investigation: M.N., M.S., K.T., J.R., A.L., M.P.W., Formal Analysis: M.N., M.S., J.R., A.L., Writing – Original Draft: M.N., M.S., K. T, K.S., Review & Editing: M.N., J.R., K.S., M.P.W. Visualization: M.N., Supervision: M.P.W., Project administration: M.N., Funding acquisition: M.N. and M.P.W.

Correspondence to M. Prześniak-Welenc.

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Nadolska, M., Szkoda, M., Trzciński, K. et al. New light on the photocatalytic performance of NH4V4O10 and its composite with rGO. Sci Rep 13, 3946 (2023). https://doi.org/10.1038/s41598-023-31130-9

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Received: 21 December 2022

Accepted: 07 March 2023

Published: 09 March 2023

DOI: https://doi.org/10.1038/s41598-023-31130-9

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